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1,3-Bis(4-aminophenoxy)benzene (TPE-R) CAS 2479-46-1

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1,3-Bis(4-aminophenoxy)benzene (TPE-R) CAS 2479-46-1

Synonyms: 4,4'-(m-Phenylenedioxy)dianiline; 4,4'-[1,3-Phenylenebis(oxy)]dianiline; Resorcinol Bis(4-aminophenyl) Ether; m-Bis(p-aminophenoxy)benzene; 1,3-Bis(p-aminophenoxy)benzene; 1,3-Phenylene bis(p-aminophenyl) ether; 

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Product Details

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1,3-Bis(4-aminophenoxy)benzene (TPE-R), CAS 2479-46-1, is an aromatic diamine monomer with a phenyl ether core and flexible linkages, enabling the synthesis of high-performance polymers like polyimides with excellent thermal stability, mechanical strength, processability, and flame retardancy.

Basic Information of TPE-R

Product Name1,3-Bis(4-aminophenoxy)benzene
Abbreviation

TPE-R

CAS Number

2479-46-1

Molecular FormulaC18H16N2O2
Molecular Weight292.33 g/mol
AppearanceWhite to brown powder to crystal
Purity≥99%
Package1kg/bottle, 20kg/drum, or customized
Molecular formulaTPE-R Molecular Structure

 

Key Properties

  • Reasonable thermal stability for aromatic diamines

  • Rigidity from aromatic phenoxy linkages

  • Dual amine groups suitable for polymerization / crosslinking

  • Good compatibility with dianhydrides / comonomers

  • Moderate processability in suitable solvents


Key Applications of TPE-R

  • High-Performance Polymers: Serves as a diamine monomer for synthesizing semicrystalline polyimides (e.g., with BPDA or PMDA) and copolymers, offering melt-processability and high-temperature resistance for aerospace composites, structural adhesives, and engineering plastics in military and industrial sectors.

  • Electronics and Electrical Insulation: Utilized in polyimide films, resins, and composites for microelectronics, 5G devices, smartphones, and electromagnetic shielding (e.g., with titanate nanotubes), providing low dielectric constants and high thermal resistance.

  • Fuel Cell Membranes: Copolymerized with monomers like PEG to produce membranes with high proton conductivity (up to 210 mS/cm) and thermal stability (up to 140°C), suitable for polymer electrolyte fuel cells.

  • Sensors and Coordination Compounds: Acts as a ligand in metal-organic complexes (0D, 1D, 2D) for sensing nitroaromatic compounds; also used in siloxane-organic networks for advanced materials.

  • Other Industrial Uses: Employed as a curing/crosslinking agent in epoxy resins, powder coating matting agents, PVC plasticizers, and in supramolecular chemistry for thiourea derivatives and hydrogen-bonded assemblies; potential in pharmaceuticals and dyes.


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