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2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP) CAS 69563-88-8

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2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP) CAS 69563-88-8

Synonyms: 4-BDAF; 6FBAPP; BAPOFP; BIS-AF-A; 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline; 4,4′-(Hexafluoroisopropylidene)bis[(4-aminophenoxy)benzene]; 4′,4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline); Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis-

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Product Details

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2,2'-Bis(4-aminophenoxyphenyl)propane (BAPP), CAS 13080-86-9, is a diamine monomer featuring flexible ether linkages and a propane core, enabling the synthesis of high-performance polymers with excellent thermal stability, mechanical strength, flexibility, and solubility.

Basic Information of HFBAPP

Product Name2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane
Abbreviation

HFBAPP

CAS Number69563-88-8
Molecular FormulaC27H20F6N2O2
Molecular Weight518.45 g/mol
AppearanceWhite to almost white powder to crystal
Purity≥99%
Package1kg/bottle, 20kg/drum, or customized
Molecular formulaHFBAPP Molecular Structure;

 

Key Properties

  • Excellent thermal stability and high glass transition when polymerized

  • Fluorinated backbone gives low dielectric constant and good chemical stability

  • Rigid aromatic structure for mechanical strength

  • Suitable for incorporation in high-temperature polymer systems

  • Good processability in appropriate solvents / reaction media


Key Applications of HFBAPP

  • High-Performance Polymers: Used as a monomer for synthesizing polyimides and polyetherimides with excellent thermal and mechanical properties, applied in aerospace composites, aviation materials, and high-temperature environments.

  • Gas Separation Membranes: Incorporated into permeable polyimide membranes for CO₂ capture from the atmosphere and gas transport/separation, leveraging its fluorination for enhanced selectivity and permeability.

  • Electronics and Optoelectronics: Serves as a building block for low-dielectric polyimides in telecommunication devices, flexible substrates for solar cells (achieving power conversion efficiencies up to 16.1%), and capacitors; also used in microelectronics, liquid crystal displays, and laser materials.

  • Energy Storage and Advanced Materials: Utilized in polyetherimides for capacitive energy storage (discharge density of 3.6 J/cm³, efficiency 96.5%); also applied in covalent organic frameworks (COFs), specialty coatings, and nanotechnology.


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